(2,2′-Bipyridyl-κ2N,N′)bis(N-butyl-N-methyldithiocarbamato-κ2S,S′)cadmium(II)
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(2,2′-Bipyridyl-κ2 N,N′)bis(N-butyl-N-methyldithiocarbamato-κ2 S,S′)cadmium(II)
The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H⋯S inter-actions and...
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In the title benzamide derivative, C(11)H(14)ClNO, the chloro-benzene and butyl-amine groups are each planar, with mean deviations from the planes of 0.013 and 0.030 Å, respectively, and a dihedral angle of 2.54 (9)° between the two planes. In the crystal structure, N-H⋯O hydrogen bonds link mol-ecules in rows along a. Short inter-molecular Cl⋯Cl inter-actions [3.4225 (5) Å] link these rows int...
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1.1.3 Chemical and physical properties of the pure substance From American Conference of Governmental Industrial Hygienists (1991) unless otherwise noted. (a) Description: Colourless, flammable liquid (b) Boiling-point: 145°C (Lide, 1997) (c) Melting-point: –64.6°C (Lide, 1997) (d) Solubility: Very slightly soluble in water (0.14% at 20°C); soluble in ethanol, diethyl ether and acetone (e) Vapo...
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The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa-hedral environment. The Cl ligands are cis. Two intramolecular C-H⋯Cl hydrogen bonds occur in...
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In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni(2+) ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H⋯O and O-H⋯O hydrogen bonds and aromatic π-π stack...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811006878